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Adjective: vinegarish  vi-nu-gu-rish
  1. Tasting or smelling like vinegar
    "The vinegarish flavour of the dressing complemented the salad";
    - acetose, acetous, vinegary
     
  2. Having a sour disposition; ill-tempered
    "Her vinegarish remarks soured the mood of the meeting";
    - vinegary

See also: ill-natured, sour