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Adjective: clearheaded  'kleer'he-did
  1. Not mentally confused; able to think clearly and act intelligently
    "I've never felt more clearheaded and sure in my life";
    - clear-thinking
Noun: clear-headedness
  1. The state of being clear-headed
    "Her clear-headedness in crisis situations made her an excellent emergency responder"

See also: clear, unclouded