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Adjective: unapproachable  ,ún-u'prow-chu-bul
  1. Discouraging intimacies; reserved
    "an unapproachable executive"
     
  2. Inaccessibly located or situated
    "an unapproachable chalet high in the mountains";
    - unreachable, unreached, out of reach

See also: inaccessible, offish, standoffish, unaccessible [rare]

Antonym: approachable