WordWeb Online

1. Conspicuously new
   "shiny spic-and-span shoes";
   - brand-new, bran-new, spick-and-span
    
2. Completely neat and clean
   "the apartment was spic-and-span";
   - immaculate, speckless, spick-and-span, spic, spick, spotless

See also: clean, new