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Adjective: round-eyed  'rawnd,Id
  1. Exhibiting childlike simplicity and credulity
    "listened in round-eyed wonder";
    - childlike, wide-eyed, dewy-eyed, simple
     
  2. Having large round wide-open eyes
    - saucer-eyed

See also: eyed, naif, naïf, naive, naïve