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Adjective: kitty-cornered  'ki-tee,kor-nurd
Usage: N. Amer
  1. Positioned diagonally across from something
    "The store was located kitty-cornered to the town square";
    - catacorner [N. Amer], cata-cornered [N. Amer], catercorner [N. Amer], cater-cornered [N. Amer], catty-corner [N. Amer], catty-cornered [N. Amer], kitty-corner [N. Amer]

See also: oblique